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Chlorobis(cyclooctene)iridium dimer : ウィキペディア英語版 | Chlorobis(cyclooctene)iridium dimer
Chlorobis(cyclooctene)iridium dimer is an organoiridium compound with the formula Ir2Cl2(C8H14)4, where C8H14 is ''cis''-cyclooctene. Sometimes abbreviated Ir2Cl2(coe)4, it is a yellow, air-sensitive solid that is used as a precursor to many other organoiridium compounds and catalysts. The compound is prepared by heating an alcohol solution of sodium hexachloroiridate with cyclooctene in ethanol.〔Van der Ent, A.; Onderdelinden, A. L. "Chlorobis(cyclooctene)rhodium(I) and di-μ-chlorobis() (I) complexes" Inorganic Syntheses 1973, volume 14, pp. 92-5. 〕 The coe ligands are easily displaced by other more basic ligands, more so than the diene ligands in the related complex cyclooctadiene iridium chloride dimer. ==References== 〔
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